Activation of “Inert” Alkenyl/Aryl CO Bond and Its Application in Cross‐Coupling Reactions

2011/01/17 by Bi‐Jie Li, Da‐Gang Yu, Chang‐Liang Sun +1 · 1 citation
Chemistry · #Catalytic Cross-Coupling Reactions #Catalytic C–H Functionalization Methods #Sulfur-Based Synthesis Techniques

paper · doi:10.1002/chem.201002273

openalex publication_date 2011/01/17 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/22

Abstract

Enol and phenol functionalities are very common in organic molecules. Utilization of these materials is very appealing in organic synthesis because they are important alternatives to organohalides in cross-coupling reactions. In this review, we summarize the transition-metal-catalyzed cross-coupling of enol- and phenol-based electrophiles, including phosphates, sulfonates, ethers, carboxylates, and phenolates.

Citations

• Asymmetric Transition Metal-Catalyzed Allylic Alkylations
• Asymmetric Transition-Metal-Catalyzed Allylic Alkylations: Applications in Total Synthesis
• Palladium(0)-Catalyzed Cross-Coupling Reaction of Alkoxydiboron with Haloarenes: A Direct Procedure for Arylboronic Esters

Cited by

• Phosphonium coupling [wikipedia]

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