Transition metal-catalysed cross-coupling reactions of P-activated enols

2011/01/01 by Jonathan D. Sellars, Patrick G. Steel · 1 citation
Chemistry · #Catalytic C–H Functionalization Methods #Catalytic Cross-Coupling Reactions #Sulfur-Based Synthesis Techniques

paper · doi:10.1039/c1cs15100b

openalex publication_date 2011/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/15

Abstract

Transition metal catalysed cross-coupling reactions are ubiquitous in organic chemistry providing an impressive technique for C-C bond formation. Whilst many electrophilic partners have been described for these reactions, aryl and vinyl phosphates, phosphonates and phosphonites can offer advantages in terms of preparation, stability and reactivity profile. This critical review summarises the advances made to date utilising P-activated enols in metal-catalysed cross-coupling reactions (97 references).

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• Phosphonium coupling [wikipedia]

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