Transition-Metal-Catalyzed C-P Cross-Coupling Reactions

2010/08/04 by Martin Oestreich, Florian Tappe, Florian M. J. Tappe +2
Chemistry · #Catalytic Cross-Coupling Reactions #Catalytic C–H Functionalization Methods #Asymmetric Hydrogenation and Catalysis

paper · doi:10.1055/s-0030-1257960

Abstract

This review is a comprehensive account of transition-metal-catalyzed cross-coupling reactions to form C-P bonds. Organized according to the hybridization of the carbon coupling partner, the numerous phosphorus coupling partners are discussed individually. The several putative mechanisms of these transition-metal catalyses are also included, thereby providing insights into both the synthetic and the mechanistic aspects of this chemistry. A separate section is devoted to asymmetric C-P cross-couplings.

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