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1. A Complementary Toolbox of Iterative Methods for the Stereoselective Synthesis of Heteroatom-Rich Motives from C1-Building Blocks
   2018/05/15 by Christoph Hirschhäuser, Sujenth Kirupakaran, Hans-Gert Korth +1 · 26 citations
   Chemistry · #Alkyl #Asymmetric Hydrogenation and Catalysis #Asymmetric Synthesis and Catalysis #Carbenoid #Catalysis #Chemistry #Combinatorial chemistry #Cyclopropane Reaction Mechanisms #Enantioselective synthesis #Heteroatom #Nucleophile #Organic chemistry #Reagent #Stereocenter #Stereochemistry #Substrate (aquarium) #Umpolung
2. 4-Halo-2-azabuta-1,3-dienes as intermediates in the rhodium carbenoid-initiated transformation of 2-halo-2H-azirines into 2,3-dihydroazetes and 2,5-dihydrooxazoles
   2015/05/13 by Ilia A. Smetanin, Михаил С. Новиков, Mikhail S. Novikov +6 · 47 citations
   Chemistry · #Azirine #Carbenoid #Catalysis #Catalytic C–H Functionalization Methods #Chemistry #Cyclopropane Reaction Mechanisms #Diazo #Medicinal chemistry #Moiety #Organic chemistry #Rhodium #Ring (chemistry) #Stereochemistry #Stereoselectivity #Synthesis and Catalytic Reactions #Ylide
3. (Chloromethyl)magnesium Chloride–Lithium Chloride: A Chemoselective Reagent for the Synthesis of Functionalized Aromatic Chlorohydrins
   2015/03/04 by Giuliano Clososki, Giuliano C. Clososki, Rodolfo Nishimura +5 · 24 citations
   Chemistry · #Asymmetric Synthesis and Catalysis #Carbenoid #Catalysis #Chemistry #Chloride #Coordination Chemistry and Organometallics #Cyclopropane Reaction Mechanisms #Inorganic chemistry #Lithium (medication) #Lithium chloride #Magnesium #Organic chemistry #Reactivity (psychology) #Reagent #Rhodium
4. Selective syntheses of 2H-1,3-oxazines and 1H-pyrrol-3(2H)-ones via temperature-dependent Rh(II)-carbenoid-mediated 2H-azirine-ring expansion
   2014/04/04 by Kirill V. Zavyalov, Mikail S. Novikov, Михаил С. Новиков +3 · 30 citations
   Chemistry · #Azirine #Carbenoid #Catalysis #Chemistry #Cyclopropanation #Cyclopropane Reaction Mechanisms #Diazo #Ethyl diazoacetate #Isoindole #Medicinal chemistry #Organic chemistry #Oxazines #Photochemistry #Pyrrole #Rhodium #Ring (chemistry) #Stereochemistry #Synthesis and Catalytic Reactions #Synthesis of β-Lactam Compounds #Ylide
5. Rh(II)-carbenoid mediated 2H-azirine ring-expansion as a convenient route to non-fused photo- and thermochromic 2H-1,4-oxazines
   2013/04/02 by Николай В. Ростовский, Nikolai V. Rostovskii, Mikhail S. Novikov +4 · 42 citations
   Chemistry · #Carbenoid #Catalysis #Catalytic C–H Functionalization Methods #Chemistry #Cyclopropane Reaction Mechanisms #Double bond #Isomerization #Medicinal chemistry #Organic chemistry #Oxazines #Photochemistry #Rhodium #Ring (chemistry) #Stereochemistry #Stereoselectivity #Synthesis and Catalytic Reactions #Yield (engineering) #Ylide
6. Asymmetric Total Synthesis of (+)-Codeine via Intramolecular Carbenoid Insertion
   1999/09/25 by James D. White, Peter Hrnčiar, Frank Stappenbeck · 71 citations
   Chemistry · #Annulation #Asymmetric Synthesis and Catalysis #Beckmann rearrangement #Benzofuran #Carbenoid #Catalysis #Chemical synthesis and alkaloids #Chemistry #Cyclopropane Reaction Mechanisms #Enantiomer #Enantioselective synthesis #Intramolecular force #Lactam #Medicinal chemistry #Organic chemistry #Oxime #Stereochemistry #Tetralone #Total synthesis