Selective syntheses of 2H-1,3-oxazines and 1H-pyrrol-3(2H)-ones via temperature-dependent Rh(II)-carbenoid-mediated 2H-azirine-ring expansion

2014/04/04 by Kirill V. Zavyalov, Mikail S. Novikov, Михаил С. Новиков +3 · 30 citations
Chemistry · #Azirine #Carbenoid #Catalysis #Chemistry #Cyclopropanation #Cyclopropane Reaction Mechanisms #Diazo #Ethyl diazoacetate #Isoindole #Medicinal chemistry #Organic chemistry #Oxazines #Photochemistry #Pyrrole #Rhodium #Ring (chemistry) #Stereochemistry #Synthesis and Catalytic Reactions #Synthesis of β-Lactam Compounds #Ylide

paper · doi:10.1016/j.tet.2014.03.101

published in Tetrahedron 70(21), 3377-3384 (Elsevier BV)

openalex publication_date 2014/04/04 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Citations

• Efficient route to 2H-1,3-oxazines through ring expansion of isoxazoles by rhodium carbenoids

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