Reactions of [HOs3(CO)10(µ-L)] (L = saccharinate, thiosaccharinate) with Ph3SnH and Ph3GeH

2021/04/10 by Md. Selim Reza, Md Selim Reza, Shishir Ghosh · 3 citations
Chemistry · #Organometallic Compounds Synthesis and Characterization #Organometallic Complex Synthesis and Catalysis #Inorganic Chemistry and Materials

paper · doi:10.1016/j.jorganchem.2021.121819

Citations

• Oxidative-addition of germanium–hydrogen bonds to triosmium centers: Reactions of Os3(CO)10(μ-dppm) and Os3(CO)8(μ3-Ph2PCH2P(Ph)C6H4)(μ-H) with Ph3GeH
• Oxidative-addition of the N–H bond of saccharin (sacH) to a triosmium centre: Synthesis, structure and reactivity of Os3(CO)10(μ-H)(μ-sac)
• OLEX2: a complete structure solution, refinement and analysis program
• Reactions of [Os3(CO)10(μ-dppm)] and [HOs3(CO)8μ3-Ph2PCH2P(Ph)C6H4] with Bu3GeH: Ge–H and Ge–C bond cleavage at triosmium centers
• Facile Os-Os bond cleavage in the reactions of [Os3(CO)10(NCMe)2] and [Os3(CO)10(μ-H)2] with tetramethylthiuram disulfide (tmtd): Syntheses and crystal structures of new polynuclear osmium carbonyl complexes containing a dimethyldithiocarbamate ligand(s)

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• Tri and hexaosmium clusters bearing saccharinate and diphosphine ligands: Synthesis, structure and fluxionality
• Reactivity studies of saccharin at a diphosphine-stabilized low-valent triruthenium center to show a new, simple but elusive coordination mode of saccharinate ligand
• Triosmium cluster bearing a metalated dibenzylideneacetone ligand: Synthesis, structure, redox and electronic properties