Tri and hexaosmium clusters bearing saccharinate and diphosphine ligands: Synthesis, structure and fluxionality

2024/05/31 by Md. Sohag Hasan, Md. Mahbub Alam, Mir Khaleda Parvin +4 · 1 citation
Chemistry · Materials Science · #Organometallic Complex Synthesis and Catalysis #Nanocluster Synthesis and Applications #Asymmetric Hydrogenation and Catalysis

paper · doi:10.1016/j.jorganchem.2024.123212

Citations

• Oxidative-addition of the N–H bond of saccharin (sacH) to a triosmium centre: Synthesis, structure and reactivity of Os3(CO)10(μ-H)(μ-sac)
• <i>OLEX2</i>: a complete structure solution, refinement and analysis program
• Reactions of [HOs3(CO)10(µ-L)] (L = saccharinate, thiosaccharinate) with Ph3SnH and Ph3GeH

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• Reactivity studies of saccharin at a diphosphine-stabilized low-valent triruthenium center to show a new, simple but elusive coordination mode of saccharinate ligand