Reactivity studies of saccharin at a diphosphine-stabilized low-valent triruthenium center to show a new, simple but elusive coordination mode of saccharinate ligand

2025/12/25 by Jannatul F. Raka, Nahid Akter, Md. Mahbub Alam +4
Chemistry · #Organometallic Complex Synthesis and Catalysis #Catalytic Cross-Coupling Reactions #N-Heterocyclic Carbenes in Organic and Inorganic Chemistry

paper · doi:10.1016/j.jorganchem.2025.123994

Citations

• Oxidative-addition of the N–H bond of saccharin (sacH) to a triosmium centre: Synthesis, structure and reactivity of Os3(CO)10(μ-H)(μ-sac)
• The chemistry of [M3(CO)10(μ-dppm)](M=Ru, Os): Activating and maintaining the trinuclear core
• OLEX2: a complete structure solution, refinement and analysis program
• Reactions of [HOs3(CO)10(µ-L)] (L = saccharinate, thiosaccharinate) with Ph3SnH and Ph3GeH
• Tri and hexaosmium clusters bearing saccharinate and diphosphine ligands: Synthesis, structure and fluxionality