Novel One-Pot Synthesis of Thiophenols from Related Triazenes under Mild Conditions

2012/07/23 by Masoud Kazem‐Rostami, Ardeshir Khazaei, Ahmad Reza Moosavi‐Zare +2 · 1 citation
Chemistry · Environmental Science · #Aryl #Catalysis #Chemistry #Chemistry and Chemical Engineering #Combinatorial chemistry #Counterion #Diazonium Compounds #Hydrogen sulfide #Ion #Nucleophile #Organic Chemistry Cycloaddition Reactions #Organic chemistry #Primary (astronomy) #Sodium sulfide #Sulfide #Sulfur #Sulfur-Based Synthesis Techniques #Triazene

paper · doi:10.1055/s-0032-1316557

openalex publication_date 2012/07/23 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/04

Abstract

In this work, at first, triazenes were synthesized from primary aryl amines. Afterwards, triazenes were converted into the corresponding thiophenols in one-pot using sodium sulfide in acidic media, by in situ generation of diazonium counterion beside hydrogen sulfide as anionic sulfur nucleophile at room temperature. The procedure can be a convenient shortcut for the preparation of thiophenols from primary aryl amines.

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• Hydrogen sulfide [wikipedia]

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