Technetium Fluoride Trioxide, TcO3F, Preparation and Properties

2007/06/05 by Joanna Supeł, Ulrich Abram, Adelheid Hagenbach +1 · 1 citation
Chemistry · Engineering · Materials Science · #Gas Sensing Nanomaterials and Sensors #Inorganic Fluorides and Related Compounds #Luminescence Properties of Advanced Materials

paper · doi:10.1021/ic070333y

openalex publication_date 2007/06/05 · openalex created_date 2019/06/27 · openalex updated_date 2026/06/26

Abstract

TcO4- in HF solution reacts to form Tc3O9F4- along with some TcO3F. Pure TcO3F is obtained if a mixture of HF/BiF5 is applied. TcO3F dimerizes in the solid state via fluoride bridges, similar to the structures of CrO2F2 and VOF3. TcO3F reacts in HF with AsF5 or SbF5 under formation of TcO2F2+As(Sb)F6-.

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• Chromyl fluoride [wikipedia]

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