The oxidation of carbonate green rust into ferric phases:solid-state reaction or transformation via solution

2004/08/27 by Ludovic Legrand, L. Mazérolles, Léo Mazerolles +1 · 3 citations
Chemistry · Energy · Engineering · #Environmental remediation with nanomaterials #Iron oxide chemistry and applications #Radioactive element chemistry and processing

paper · doi:10.1016/j.gca.2004.02.019

openalex publication_date 2004/08/27 · crossref created 2004/08/27 · crossref issued 2004/09/01 · crossref published 2004/09/01 · crossref published-print 2004/09/01 · crossref deposited 2019/02/04 · openalex created_date 2025/10/10 · crossref indexed 2026/07/11 · openalex updated_date 2026/07/22

Citations

• Über Die dunkelgrünen Hydroxyverbindungen des Eisens
• Preparation and Eh--pH diagrams of Fe(II)--Fe(III) green rust compounds; hyperfine interaction characteristics and stoichiometry of hydroxy-chloride, -sulphate and -carbonate
• The corrosion of mild steel in boiling salt solutions
• Synthesis of Fe(II-III) hydroxysulphate green rust by coprecipitation
• Conversion electron Mössbauer spectroscopy and X-ray diffraction studies of the formation of carbonate-containing green rust one by corrosion of metallic iron in NaHCO3 and (NaHCO3 + NaCl) solutions
• The region of stability of green rust II in the electrochemical potential-pH equilibrium diagram of iron in sulphate medium
• The mechanism of oxidation of ferrous hydroxide in sulphated aqueous media: Importance of the initial ratio of the reactants
• Electrochemical and Raman spectroscopic studies of the influence of chlorinated solvents on the corrosion behaviour of iron in borate buffer and in simulated groundwater
• On the stoichiometry and pourbaix diagram of Fe(II)-Fe(III) hydroxy-sulphate or sulphate-containing green rust 2: An electrochemical and Mössbauer spectroscopy study
• The crystal structure of pyroaurite
• Study of oxidation products formed on iron in solutions containing bicarbonate/carbonate
• Reduction of nitrate to ammonium by sulphate green rust: activation energy and reaction mechanism
• Etude de l'Oxydation par Aeration de Fe(OH)2 en Milieu Chlorure
• Crystal structure of green rust formed by corrosion of cast iron
• The preparation and thermodynamic properties of Fe(II)Fe(III) hydroxide-carbonate (green rust 1); Pourbaix diagram of iron in carbonate-containing aqueous media
• The Oxides and Hydroxides of Iron and Their Structural Inter-Relationships
• Composition, stabilization, and light absorption of Fe(II)Fe(III) hydroxy-carbonate (‘green rust’)
• Biogenic iron mineralization accompanying the dissimilatory reduction of hydrous ferric oxide by a groundwater bacterium

Cited by

• Fougerite, a new mineral of the pyroaurite-iowaite group: Description and crystal structure
• Fougerite and FeII–III hydroxycarbonate green rust; ordering, deprotonation and/or cation substitution; structure of hydrotalcite-like compounds and mythic ferrosic hydroxide
• Green rust [wikipedia]