The mechanism of oxidation of ferrous hydroxide in sulphated aqueous media: Importance of the initial ratio of the reactants

1991/01/01 by A. A. Olowe, A.A Olowe, J.-M. R. Génin +1 · 10 citations
Energy · Engineering · Materials Science · #Corrosion Behavior and Inhibition #Iron oxide chemistry and applications #Metal Extraction and Bioleaching

paper · doi:10.1016/0010-938x(91)90016-i

crossref issued 1991/01/01 · crossref published 1991/01/01 · crossref published-print 1991/01/01 · openalex publication_date 1991/01/01 · crossref created 2003/06/20 · crossref deposited 2019/03/20 · openalex created_date 2025/10/10 · crossref indexed 2026/03/15 · openalex updated_date 2026/06/26

Citations

• Über Die dunkelgrünen Hydroxyverbindungen des Eisens
• The region of stability of green rust II in the electrochemical potential-pH equilibrium diagram of iron in sulphate medium
• The Oxides and Hydroxides of Iron and Their Structural Inter-Relationships

Cited by

• Evidence for the Fe(II)-Fe(III) Green Rust "Fougerite" Mineral Occurrence in a Hydromorphic Soil and Its Transformation with Depth
• The influence of temperature on the oxidation of ferrous hydroxide in sulphated aqueous medium: Activation energies of formation of the products and hyperfine structure of magnetite
• Conversion electron Mössbauer spectroscopy and X-ray diffraction studies of the formation of carbonate-containing green rust one by corrosion of metallic iron in NaHCO3 and (NaHCO3 + NaCl) solutions
• Preparation and Eh--pH diagrams of Fe(II)--Fe(III) green rust compounds; hyperfine interaction characteristics and stoichiometry of hydroxy-chloride, -sulphate and -carbonate
• The preparation and thermodynamic properties of Fe(II)Fe(III) hydroxide-carbonate (green rust 1); Pourbaix diagram of iron in carbonate-containing aqueous media
• The oxidation of carbonate green rust into ferric phases:solid-state reaction or transformation via solution
• On the stoichiometry and pourbaix diagram of Fe(II)-Fe(III) hydroxy-sulphate or sulphate-containing green rust 2: An electrochemical and Mössbauer spectroscopy study
• On the formation of β-FeOOH (akaganéite) in chloride-containing environments
• Fougerite and FeII–III hydroxycarbonate green rust; ordering, deprotonation and/or cation substitution; structure of hydrotalcite-like compounds and mythic ferrosic hydroxide
• Green rust [wikipedia]