The Oxides and Hydroxides of Iron and Their Structural Inter-Relationships

1959/01/01 by J. D. Bernal · 19 citations
Energy · Environmental Science · #Iron oxide chemistry and applications #Minerals Flotation and Separation Techniques

paper · doi:10.1180/claymin.1959.004.21.02

openalex publication_date 1959/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/17

Abstract

The transformations ia-x the iron oxide-hydroxide system have been inter-preted in a rational crystallochemical manner, some bring characterized as topotactic and some as non-topotacfic. Crystallographic measure-ments have been made on the more reactive or metastable phases, parti-cularly on the "green rusts. " The oxyhydroxides ~-]~eOOFI and ~-FeOOH have been examined more fully, but data on ald the phases have been checked. New data on transformations, such as FeCOa---> FeO and Fe(OH)~-+ FeO are reported.

Cited by

• Composition, stabilization, and light absorption of Fe(II)Fe(III) hydroxy-carbonate (‘green rust’)
• The region of stability of green rust II in the electrochemical potential-pH equilibrium diagram of iron in sulphate medium
• The corrosion of mild steel in boiling salt solutions
• Conversion electron Mössbauer spectroscopy and X-ray diffraction studies of the formation of carbonate-containing green rust one by corrosion of metallic iron in NaHCO3 and (NaHCO3 + NaCl) solutions
• Preparation and Eh--pH diagrams of Fe(II)--Fe(III) green rust compounds; hyperfine interaction characteristics and stoichiometry of hydroxy-chloride, -sulphate and -carbonate
• The preparation and thermodynamic properties of Fe(II)Fe(III) hydroxide-carbonate (green rust 1); Pourbaix diagram of iron in carbonate-containing aqueous media
• The oxidation of carbonate green rust into ferric phases:solid-state reaction or transformation via solution
• Synthesis of Fe(II-III) hydroxysulphate green rust by coprecipitation
• On the stoichiometry and pourbaix diagram of Fe(II)-Fe(III) hydroxy-sulphate or sulphate-containing green rust 2: An electrochemical and Mössbauer spectroscopy study
• Evidence for the Fe(II)-Fe(III) Green Rust "Fougerite" Mineral Occurrence in a Hydromorphic Soil and Its Transformation with Depth
• The mechanism of oxidation of ferrous hydroxide in sulphated aqueous media: Importance of the initial ratio of the reactants
• Ferric hydrous oxide sols
• Mineralogical constitution of colloidal “hydrous ferric oxides”
• The cobalt hydroxide electrode—I. Structure and phase transitions of the hydroxides
• β-Ferric Oxyhydroxide
• Reduction of SeO42- Anions and Anoxic Formation of Iron(II)−Iron(III) Hydroxy-Selenate Green Rust
• Fougerite, a new mineral of the pyroaurite-iowaite group: Description and crystal structure
• Fougerite and FeII–III hydroxycarbonate green rust; ordering, deprotonation and/or cation substitution; structure of hydrotalcite-like compounds and mythic ferrosic hydroxide
• Green rust [wikipedia]