Sayago-- al otro lado de la leyenda

1996/01/01 by William J. Evans, Stosh A. Kozimor, Joseph W. Ziller +1 · 10 citations
Arts and Humanities · Chemistry · Medicine · #Comparative Literary Analysis and Criticism #Cultural and Mythological Studies #Organometallic Complex Synthesis and Catalysis #Radioactive element chemistry and processing #Radiopharmaceutical Chemistry and Applications #Spanish Literature and Culture Studies

paper · doi:10.1126/science.1116452

openalex publication_date 1996/01/01 · openalex created_date 2016/06/24 · openalex updated_date 2026/04/28

Abstract

Uranium nitrides offer potential as future nuclear fuels and as probes of metal ligand multiple bonding involving the f-block actinide metals. However, few molecular examples are available for study owing to the difficulties in synthesis. Recent advances in organoactinide chemistry have provided a route to uranium nitride complexes that expands the options for developing UN chemistry. Several 24-membered uranium nitrogen rings, (UNUN3)4, have been synthesized by reduction of sodium azide with organometallic metallocene derivatives, [(C5Me4R)2U][(mu-Ph)2BPh2] (R = Me, H; Me = methyl, Ph = phenyl). The nanometer-sized rings contain unusual UNU nitride linkages that have short U-N distances within the double-bond range.

Citations

• Synthesis and Properties of High-Valent Organouranium Complexes Containing Terminal Organoimido and Oxo Functional Groups. A New Class of Organo-f-Element Complexes

Cited by

• Uranium−Nitrogen Multiple Bonding: The Case of a Four-Coordinate Uranium(VI) Nitridoborate Complex
• Synthesis and Structure of a Terminal Uranium Nitride Complex
• Uranium azide photolysis results in C–H bond activation and provides evidence for a terminal uranium nitride
• First-principles study of single-crystal uranium mono- and dinitride
• A Nitrido‐Centered Uranium Azido Cluster Obtained from a Uranium Azide
• Simple NUF3 and PUF3 Molecules with Triple Bonds to Uranium
• Isolation and characterization of a uranium(VI)–nitride triple bond
• A Weak Interaction between Iron and Uranium in Uranium Alkyl Complexes Supported by Ferrocene Diamide Ligands
• Uranium−Nitrogen Multiple Bonding: Isostructural Anionic, Neutral, and Cationic Uranium Nitride Complexes Featuring a Linear U═N═U Core
• Uranium nitrides [wikipedia]