Simple NUF3 and PUF3 Molecules with Triple Bonds to Uranium

2008/07/07 by Lester Andrews, Xuefeng Wang, Roland Lindh +2 · 6 citations
Chemistry · Materials Science · #Catalytic Processes in Materials Science #Inorganic Fluorides and Related Compounds #Radioactive element chemistry and processing

paper · doi:10.1002/anie.200801120

openalex publication_date 2008/07/07 · openalex created_date 2016/06/24 · openalex updated_date 2026/07/22

Abstract

UN-beatable? Laser-ablated uranium atoms activate NF3 and PF3 to form the NUF3 and PUF3 molecules containing novel terminal nitride and phosphide functional groups. These molecules are identified from matrix infrared spectra and theoretical methods. The NUF3 molecule contains the strongest triple bond to uranium in a ternary compound.

Citations

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• Synthesis and Structure of a Terminal Uranium Nitride Complex
• Uranium−Nitrogen Multiple Bonding: The Case of a Four-Coordinate Uranium(VI) Nitridoborate Complex
• Uranium−Nitrogen Multiple Bonding: Isostructural Anionic, Neutral, and Cationic Uranium Nitride Complexes Featuring a Linear U═N═U Core
• Uranium nitrides [wikipedia]