A Nitrido‐Centered Uranium Azido Cluster Obtained from a Uranium Azide

2008/03/10 by Grégory Nocton, Jacques Pécaut, Marinella Mazzanti · 5 citations
Chemistry · Materials Science · #Inorganic Chemistry and Materials #Lanthanide and Transition Metal Complexes #Radioactive element chemistry and processing

paper · doi:10.1002/anie.200705742

openalex publication_date 2008/03/10 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/22

Abstract

Caught in the actinide: A tetranuclear azido/nitrido uranium anion containing eight end-on bridging azido ligands and a μ4 interstitial nitrido ligand has been isolated and structurally characterized (see 1D chain; U green, Cs orange, I magenta, N blue, C white). A new two-step procedure has been developed to promote the cluster assembly by oxidation of [UI3(thf)4] with a preformed uranium heptaazido complex.

Citations

• Sayago-- al otro lado de la leyenda

Cited by

• Isolation and characterization of a uranium(VI)–nitride triple bond
• Synthesis and Structure of a Terminal Uranium Nitride Complex
• Uranium−Nitrogen Multiple Bonding: The Case of a Four-Coordinate Uranium(VI) Nitridoborate Complex
• Uranium−Nitrogen Multiple Bonding: Isostructural Anionic, Neutral, and Cationic Uranium Nitride Complexes Featuring a Linear U═N═U Core
• Uranium nitrides [wikipedia]