2010/10/15 by R. R. Kostikov, Sánchez-Sancho Francisco, Marı́a Garranzo +1 · 2 citations
Chemistry · #Synthetic Organic Chemistry Methods #Asymmetric Synthesis and Catalysis #Carbohydrate Chemistry and Synthesis
paper · doi:10.1002/047084289x.rd068.pub2
openalex publication_date 2010/10/15 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/29
[585-48-8] C13H21N (MW 191.32) InChI = 1S/C13H21N/c1-12(2,3)10-8-7-9-11(14-10)13(4,5)6/h7-9H,1-6H3 InChIKey = UWKQJZCTQGMHKD-UHFFFAOYSA-N (weak base and proton scavenger;2-4 prevention of acid-catalyzed side reactions;5-7 vinyl triflate synthesis8, 9) Alternate Names: 2,6-bis(1,1-dimethylethyl)pyridine; BDMEP; DTBP;TBP. Physical Data: mp 2.2 °C; bp 100–101 °C/23 mmHg; nD20 1.4733; pKa 3.58 (50% EtOH);2 pKa 0.81 (DMSO).3 Solubility: insol H2O; sol alcohol, acetone, and hexane. Form Supplied in: colorless liquid. Handling, Storage, and Precautions: potentially toxic; handle with care. Use in a fume hood.