Postsynthetic modification of N-heterocyclic diazoolefins via backbone metallation

2026/01/01 by Bastiaan Kooij, Sebastian Nicola Lange, Farzaneh Fadaei-Tirani +2 · 1 voice
Chemistry · #Asymmetric Synthesis and Catalysis #Coordination Chemistry and Organometallics #Organometallic Complex Synthesis and Catalysis

paper · doi:10.1039/d6dt00943c

openalex publication_date 2026/01/01 · openalex created_date 2026/07/03 · openalex updated_date 2026/07/22

Abstract

backbone metallation. Reactions with electrophiles allow the regioselective introduction of silyl, phosphino, stannyl, borate, and alcoholate groups. The methodology was also used for the synthesis of a silyl-bridged bis-diazoolefin.

Discussions

• Functionalized N-heterocyclic diazoolefins. Work by Bastiaan Kooij with support from Sebastian Lange (synthesis), Rosario Scopelliti (XRD) & Farzaneh Fadaei-Tirani (XRD). Out in @daltontrans.rsc.org : [bsky, 9 points, 0 comments]

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