Gold-catalyzed Hiyama coupling of (1-silyl)allylboronates with diazonium salts

2025/11/15 by Shan Zhang, Jonas F. Wunsch, Frank Rominger +3 · 1 voice
Chemistry · #Organoboron and organosilicon chemistry #Catalytic Alkyne Reactions #Cyclopropane Reaction Mechanisms

paper · doi:10.1039/d5qo01321f

openalex created_date 2025/11/15 · openalex publication_date 2025/11/15 · openalex updated_date 2026/06/11

Abstract

The gold-catalyzed cross coupling of diazonium salts enables the selective coupling of silyl over boryl moieties.

Citations

• Standard Electrode Potentials and Temperature Coefficients in Water at 298.15 K
• Gold-Catalyzed Reactions of Specially Activated Alkynes, Allenes, and Alkenes

Discussions

• Recent research by A. Stephen K. Hashmi 𝘦𝘵 𝘢𝘭. #HeidelbergUniversity Gold catalysis enables selective silyl coupling from diazonium salts, now extended to (1-silyl)allylboronates for making valua [bsky, 0 points, 0 comments]