2025/01/01 by Assenmacher‐Maiworm, Heinz, Hahn, Jens-Uwe, Heinrich, Birgit +5
Chemistry · Environmental Science · #1 #10-(1 #10-(o-Phenylen)pyren #10-(o-Phenylen)pyrene #2 #2-Benzpyren #2-Benzpyrene #2-Phenylen)pyren #2-Phenylen)pyrene #2:5 #3 #3‐cd]pyren #3‐cd]pyrene #4 #4-Benzofluoranthen #4-Benzofluoranthene #4-Benzpyren #4-Benzpyrene #5-Benzpyren #543 Analytical chemistry #543 Analytische Chemie #571.95 Toxicology #571.95 Toxikologie #6-Dibenzanthracen #6-Dibenzanthracene #616.9803 Betriebs- und Arbeitsmedizin #616.9803 Industrial and occupational medicine #8 #9-Benzofluoranthen #9-Benzofluoranthene #Aerosol #Analysenmethode #Analytical chemistry methods development #Arbeitsplatzmessung #B[a]p #B[b]F #B[e]p #B[k]F #Benzo[a]pyren #Benzo[a]pyrene #Benzo[b]fluoranthen #Benzo[b]fluoranthene #Benzo[def]chrysen #Benzo[def]chrysene #Benzo[e]acephenanthrylen #Benzo[e]pyren #Benzo[e]pyrene #Benzo[ghi]perylen #Benzo[ghi]perylene #Benzo[k]fluoranthen #Benzo[k]fluoranthene #Benzo[k]tetraphen #Benzo[k]tetraphene #Benzo[pqr]tetraphen #Benzo[pqr]tetraphene #Bestimmungsgrenze #Dibenz[a #Dibenzo[a #Effects and risks of endocrine disrupting chemicals #Flüssigdesorption #GSP sampler #GSP-Sammler #Gefahrstoff #HPLC-FLD #Hochleistungsflüssigkeitschromatographie mit Fluoreszenzdetektion #Indeno[1 #Luft #Luftanalysen #Messbereich #PAH #PTFE filter #PTFE-Filter #Polycyclic aromatic hydrocarbons (PAH) #Polycyclische aromatische Kohlenwasserstoffe (PAK) #Probenahme #Präzision #Selektivität #Toxic Organic Pollutants Impact #Wiederfindung #aerosol #air #air analyses #analytical method #einatembare Partikelfraktion #external calibration #externe Kalibrierung #h]anthracen #h]anthracene #hazardous substance #high-performance liquid chromatography with fluorescence detection #inhalable particle fraction #limit of quantification #liquid desorption #measurement range #o-Phenylenpyren #o-Phenylenpyrene #precision #recovery #sampling #selectivity #workplace measurement
paper · doi:10.34865/am0pahse1918_w
openalex publication_date 2025/01/01 · openalex created_date 2025/12/13 · openalex updated_date 2026/07/22
This analytical method is a validated measurement procedure for the determination of six semi‐volatile polycyclic aromatic hydrocarbons (PAHs) from the EPA list (US Environmental Protection Agency) such as benzo[b]fluoranthene, benzo[k]fluoranthene, benzo[a]pyrene, dibenzo[a,h]anthracene, benzo[ghi]perylene, indeno[1,2,3‐cd]pyrene and also benzo[e]pyren in workplace air averaged over the sampling period after personal or stationary sampling. Sampling is performed by drawing a defined volume of air through a PTFE filter, which is inserted in a GSP sampling system. The collected PAH components are extracted with a mixture of acetonitrile/methanol and analysed by means of high performance liquid chromatography (HPLC) with fluorescence detection. The quantitative determination of the PAHs is based on calibration functions obtained by means of multiple‐point calibrations. The limit of quantification for an individual PAH is in the range from 0.0012 to 0.0043 µg/m3.