New Synthesis of α-Nitroso Esters and Oximes of α-Keto Esters

1988/01/01 by Syed Masarrat Ali, Yoshihiko Matsuda, Shigeo Tanimoto · 13 citations
Chemistry · #Alkyl #Catalysis #Chemistry #Chloride #Ketene #Medicinal chemistry #Nitrate #Nitrite #Nitrosation #Nitroso #Nitroso Compounds #Organic Chemistry Synthesis Methods #Organic chemistry #Oxime #Silylation #Synthesis and Reactions of Organic Compounds #Synthesis of heterocyclic compounds

paper · doi:10.1055/s-1988-27715

published in Synthesis 1988(10), 805-806 (Thieme Medical Publishers (Germany))

openalex publication_date 1988/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/04

Abstract

All articles of this category Ketene O -alkyl O ′-silyl acetals on reaction with nitric oxide or isomayl nitrite in the presence of titanium(IV) chloride provide either one of α-nitroso esters and oximes of α-keto esters.

Related

• Useful Oxidation Procedure of Oximes to Nitro Compounds with Benz-Mo in Acetonitrile
• Some Aspects of the Chemistry of Nitro Compounds
• Reaction of enol silyl ethers and enol acetates with copper(II) nitrate-iodine: synthesis of .alpha.-iodo ketones
• Convenient Oxidation of Oximes to Nitro Compounds with Sodium Perborate in Glacial Acetic Acid1
• Ligand -controlled nickel-catalyzed C–O bond cleavage of silyl enol ether for the divergent synthesis of aryl alkenes and silicon-containing product