2003/05/13 by Erik Koch, Koch, Erik, O. Gunnarsson +6
Chemistry · Engineering · Physics and Astronomy · #Advanced Thermodynamics and Statistical Mechanics #FOS: Physical sciences #Fullerene Chemistry and Applications #Materials Science (cond-mat.mtrl-sci) #Molecular Junctions and Nanostructures #Superconductivity (cond-mat.supr-con) #cond-mat.mtrl-sci #cond-mat.supr-con
paper · pdf · doi:10.48550/arxiv.cond-mat/0305274
5 pages, 3 figures; proceedings of the IWEPNM'03, Kirchberg
arxiv created 2003/05/13 · openalex publication_date 2003/05/13 · arxiv updated 2009/11/30 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28
The proposal of using the field-effect for doping organic crystals has raised enormous interest. To assess the feasibility of such an approach, we investigate the effect of a strong electric field on the electronic structure of C60 crystals. Calculating the polarization of the molecules and the splittings of the molecular levels as a function of the external field, we determine up to what field-strengths the electronic structure of C60 stays essentially unchanged, so that one can speak of field-effect doping, in the sense of putting charge carriers into otherwise unchanged states. Beyond these field strengths, the electronic structure changes so much, that on can no longer speak of a doped system. In addition, we address the question of a metal-insulator transition at integer dopings and briefly review proposed mechanisms for explaining an increase of the superconducting transition temperature in field-doped C60 that is intercalated with haloform molecules.