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New approximation to the Voigt function with applications to spectral-line profile analysis

1973/08/01 by John F. Kielkopf · 234 citations
Computer Science · Engineering · Mathematics · #Advanced Measurement and Metrology Techniques #Computer science #Envelope (radar) #Function (biology) #Geometry #Interferometry #Line (geometry) #Mathematical analysis #Mathematics #Optical measurement and interference techniques #Optics #Physics #Quantum mechanics #Spectral line #Spectral line shape #Statistics #Superposition principle #Surface Roughness and Optical Measurements #Voigt profile #Window function

paper · doi:10.1364/josa.63.000987

published in Journal of the Optical Society of America 63(8), 987 (Optica Publishing Group)

openalex publication_date 1973/08/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/05

Abstract

An approximation to the Voigt function is described, which is valid over the entire domain of the independent variables that characterize it and which is accurate to the order of 0.0001 of the peak value of the function. Relations between the parameters of the function are also given. The approximation is used to develop a procedure for fitting observed lines with Voigt functions; the class of asymmetric lines that arise from the superposition of two Voigt functions is considered in some detail, and methods for extracting the Voigt parameters of the components from the observed contour of the envelope are given. The measurement of the width and shape of a single line with a Fabry–Perot interferometer is also discussed. All of the calculations described here can be handled by programmable calculators or small computers.

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