2020/06/30 by H. Seiler, Hélène Seiler, Daniela Zahn +10 · 2 citations
Materials Science · Physics and Astronomy · #2D Materials and Applications #Anisotropy #Black phosphorus #Chemical physics #Condensed matter physics #Engineering physics #Materials science #Metallurgy #Optics #Optoelectronics #Phonon #Phosphorus #Physics #Thermal properties of materials #Topological Materials and Phenomena #cond-mat.mes-hall
paper · pdf · doi:10.1021/acs.nanolett.1c01786
arxiv created 2021/04/27 · openalex publication_date 2021/07/19 · arxiv updated 2021/08/11 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/06
We combine ultrafast electron diffuse scattering experiments and first-principles calculations of the coupled electron-phonon dynamics to provide a detailed momentum-resolved picture of lattice thermalization in black phosphorus. The measurements reveal the emergence of highly anisotropic nonthermal phonon populations persisting for several picoseconds after exciting the electrons with a light pulse. Ultrafast dynamics simulations based on the time-dependent Boltzmann formalism are supplemented by calculations of the structure factor, defining an approach to reproduce the experimental signatures of nonequilibrium structural dynamics. The combination of experiments and theory enables us to identify highly anisotropic electron-phonon scattering processes as the primary driving force of the nonequilibrium lattice dynamics in black phosphorus. Our approach paves the way toward unravelling and controlling microscopic energy flows in two-dimensional materials and van der Waals heterostructures, and may be extended to other nonequilibrium phenomena involving coupled electron-phonon dynamics such as superconductivity, phase transitions, or polaron physics.