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Degradation Behavior of Lithium-Ion Batteries During Calendar Ageing—The Case of the Internal Resistance Increase

2017/09/22 by Daniel‐Ioan Stroe, Maciej Świerczyński, S KAR +1 · 2 citations
Engineering · Chemistry · #Advanced Battery Technologies Research #Advancements in Battery Materials #Advanced Battery Materials and Technologies #Internal resistance #Battery (electricity) #Lithium (medication) #Degradation (telecommunications) #State of charge #Ion #Materials science #Energy storage #Lithium-ion battery #Depth of discharge #Range (aeronautics) #Ageing #Nuclear engineering #Electrical engineering #Chemistry #Composite material #Thermodynamics #Engineering #Physics

paper · doi:10.1109/tia.2017.2756026

openalex publication_date 2017/09/22 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/31

Abstract

Lithium-ion batteries are regarded as the key energy storage technology for both e-mobility and stationary renewable energy storage applications. Nevertheless, Lithium-ion batteries are complex energy storage devices, which are characterized by a complex degradation behavior, which affects both their capacity and internal resistance. This paper investigates, based on extended laboratory calendar ageing tests, the degradation of the internal resistance of a lithium-ion battery. The dependence of the internal resistance increase on the temperature and state-of-charge level has been extensive studied and quantified. Based on the obtained laboratory results, an accurate semiempirical lifetime model, which is able to predict with high accuracy the internal resistance increase of the lithium-ion battery over a wide temperature range and for all state-of-charge levels, was proposed and validated.

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