Consequences of diffusion-enhanced secondary reactions on ethene oligomerization rates and selectivity on H-MFI zeolites

2026/05/15 by Boen Cao, Enrique Iglesia, Rajamani Gounder · 1 citation
Chemical Engineering · Chemistry · Engineering · #Alkane #Catalysis #Catalysis and Hydrodesulfurization Studies #Catalysis and Oxidation Reactions #Diffusion #Hydrogen #Oligomer #Reaction intermediate #Reaction rate #Selectivity #Zeolite #Zeolite Catalysis and Synthesis

paper · doi:10.1016/j.jcat.2026.116962

published in Journal of Catalysis 460, 116962 (Elsevier BV)

openalex publication_date 2026/05/15 · openalex created_date 2026/05/16 · openalex updated_date 2026/07/28

Citations

• A mechanistic basis for the effects of crystallite size on light olefin selectivity in methanol-to-hydrocarbons conversion on MFI
• Catalytic reactions of dioxygen with ethane and methane on platinum clusters: Mechanistic connections, site requirements, and consequences of chemisorbed oxygen
• A mechanistic basis for the effect of aluminum content on ethene selectivity in methanol-to-hydrocarbons conversion on HZSM-5
• Isomerization and β-scission reactions of alkanes on bifunctional metal-acid catalysts: Consequences of confinement and diffusional constraints on reactivity and selectivity