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New Layered Fluorosulfide SrFBiS2

2012/08/31 by Hechang Lei, Kefeng Wang, Milinda Abeykoon +3 · 91 citations
Chemistry · Materials Science · Physics and Astronomy · #Electrical resistivity and conductivity #Inorganic Fluorides and Related Compounds #Iron-based superconductors research #Seebeck coefficient #Stacking #Superconductivity #Superconductivity in MgB2 and Alloys #Thermal conductivity #Thermoelectric effect #cond-mat.mtrl-sci #cond-mat.supr-con

paper · pdf · doi:10.1021/ic4018135

published in Inorganic Chemistry 52(18), 10685-10689 (American Chemical Society) · 6 pages, 4 figures, 1 table

openalex publication_date 2013/08/29 · arxiv created 2013/10/08 · arxiv updated 2013/10/09 · openalex created_date 2016/06/24 · openalex updated_date 2026/08/05

Abstract

We have synthesized a new layered BiS2-based compound, SrFBiS2. This compound has a similar structure to LaOBiS2. It is built up by stacking up SrF layers and NaCl-type BiS2 layers alternatively along the c axis. Electric transport measurement indicates that SrFBiS2 is a semiconductor. Thermal transport measurement shows that SrFBiS2 has a small thermal conductivity and large Seebeck coefficient. First principle calculations are in agreement with experimental results and show that SrFBiS2 is very similar to LaOBiS2, which becomes a superconductor with F doping. Therefore, SrFBiS2 may be a parent compound of new superconductors.

Citations