2006/09/19 by Jan Vorberger, Isaac Tamblyn, I. Tamblyn +4
Earth and Planetary Sciences · Physics and Astronomy · #Advanced Chemical Physics Studies #High-pressure geophysics and materials #Quantum, superfluid, helium dynamics #cond-mat.other
paper · pdf · doi:10.1103/physrevb.75.024206
13 pages, 18 figures, submitted to PRB
arxiv created 2006/09/19 · openalex publication_date 2007/01/11 · arxiv updated 2009/12/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/04
Equilibrium properties of hydrogen-helium mixtures under conditions similar to the interior of giant gas planets are studied by means of first-principles density functional molecular dynamics simulations. We investigate the molecular and atomic fluid phases of hydrogen with and without the presence of helium for densities between 0.19 and 0.66\phantom\rule0.3em0exg\phantom\rule0.2em0excm^\ensuremath-3 and temperatures from 500\phantom\rule0.3em0exto\phantom\rule0.3em0ex8000\phantom\rule0.3em0exK. Helium has a crucial influence on the ionic and electronic structure of the liquid. Hydrogen molecule bonds are shortened as well as strengthened which leads to more stable hydrogen molecules compared to pure hydrogen for the same thermodynamic conditions. The ab initio treatment of the mixture enables us to investigate the validity of the widely used linear mixing approximation. We find deviations of up to 8% in energy and volume from linear mixing at constant pressure in the region of molecular dissociation.