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Preparation and D iels– A lder Reaction of a Highly Nucleophilic Diene: trans ‐1‐Methoxy‐3‐Trimethylsiloxy‐1,3‐Butadiene and 5β‐Methoxycyclohexan‐1‐One‐3β,4β‐Dicarboxylic Acid Anhydride

2003/04/28 by Samuel J. Danishefsky, Takeshi Kitahara, P. F. SCHUDA · 1 citation
Chemistry · Biochemistry, Genetics and Molecular Biology · #Asymmetric Synthesis and Catalysis #Steroid Chemistry and Biochemistry #Synthetic Organic Chemistry Methods

paper · doi:10.1002/0471264180.os061.30

openalex publication_date 2003/04/28 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/25

Abstract

Abstract Preparation and Diels–Alder reaction of a highly nucleophilic diene: trans ‐1‐methoxy‐3‐trimethylsiloxy‐1,3‐butadiene and 5β‐methoxycyclohexan‐1‐one‐3β,4β‐dicarboxylic acid anhydride product: trans ‐1‐methoxy‐3‐trimethylsiloxy‐1,3‐butadiene product: 5β‐Methoxycyclohexan‐1‐one‐3β,4β‐dicarboxylic acid anhydride byproduct: triethylamine hydrochloride

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