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Prospects in analytical atomic spectrometry

2006/04/30 by A. A. Bol'shakov, Aleksandr A Bol'shakov, A. A. Ganeev +3 · 24 citations
Chemistry · Engineering · Physics and Astronomy · #Analytical Chemistry (journal) #Analytical chemistry methods development #Diode #Fluorescence #Instrumentation (computer programming) #Ionization #Laser #Laser ablation #Laser-induced fluorescence #Laser-induced spectroscopy and plasma #Mass Spectrometry Techniques and Applications #Mass spectrometry #physics.ins-det

paper · pdf · open access · doi:10.1070/rc2006v075n04abeh001174

published in Russian Chemical Reviews 75(4), 289-302 (Institute of Physics) · Proofread copy with an added full reference list of 279 citations. A pdf version of the final published review may be requested from Alexander Bol'shakov <[email protected]>

openalex publication_date 2006/04/30 · arxiv created 2006/07/08 · arxiv updated 2009/12/01 · openalex created_date 2016/06/24 · openalex updated_date 2026/08/05

Abstract

Tendencies in five main branches of atomic spectrometry (absorption, emission, mass, fluorescence and ionization spectrometry) are considered. The first three techniques are the most widespread and universal, with the best sensitivity attributed to atomic mass spectrometry. In the direct elemental analysis of solid samples, the leading roles are now conquered by laser-induced breakdown and laser ablation mass spectrometry, and the related techniques with transfer of the laser ablation products into inductively-coupled plasma. Advances in design of diode lasers and optical parametric oscillators promote developments in fluorescence and ionization spectrometry and also in absorption techniques where uses of optical cavities for increased effective absorption pathlength are expected to expand. Prospects for analytical instrumentation are seen in higher productivity, portability, miniaturization, incorporation of advanced software, automated sample preparation and transition to the multifunctional modular architecture. Steady progress and growth in applications of plasma- and laser-based methods are observed. An interest towards the absolute (standardless) analysis has revived, particularly in the emission spectrometry.

Citations