Photochemical generation of heteroatom (N, Si, B) or carbon radicals leveraging preinstalled carboxylic acids

2025/01/01 by Chao Tian, Lei Shi · 1 voice
Chemistry · Materials Science · #Photochromic and Fluorescence Chemistry #Photopolymerization techniques and applications #Radical Photochemical Reactions

paper · doi:10.1039/d5qo00036j

openalex publication_date 2025/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/30

Abstract

This review provides an overview of recent advancements in generating N, Si, B, and C radicals through the decarboxylation of preinstalled carboxyl substrates under visible light catalysis.

Citations

• Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
• When Light Meets Nitrogen-Centered Radicals: From Reagents to Catalysts
• Visible Light-Driven Radical-Mediated C–C Bond Cleavage/Functionalization in Organic Synthesis
• Applications of Halogen-Atom Transfer (XAT) for the Generation of Carbon Radicals in Synthetic Photochemistry and Photocatalysis
• Nitrogen-Centered Radicals in Functionalization of sp2 Systems: Generation, Reactivity, and Applications in Synthesis
• Photocatalytic C(sp3)‐H gem‐Difluoroallylation and Alkylation with Alkenes via a Base‐Assisted Formal 1,2‐Hydrogen Atom Transfer of Amidyl Radicals
• An Update on the Nitrogen Heterocycle Compositions and Properties of U.S. FDA-Approved Pharmaceuticals (2013–2023)

Discussions

• 👉Check out the hot #review by Chao Tian, Lei Shi from Harbin Institute of Technology 🔥Photochemical generation of heteroatom (N, Si, B) or carbon radicals leveraging preinstalled carboxylic acids [bsky, 0 points, 0 comments]