Modulating magnetic exchange, spin dynamics and intermacrocyclic interactions via an oxo-bridge in dihemes through stepwise oxidations

2024/12/17 by Sayantani Banerjee, Rupesh Kumar Tiwari, Paulami Chakraborty +2 · 1 voice
Chemistry · Materials Science · #Magnetism in coordination complexes #Metal-Catalyzed Oxygenation Mechanisms #Porphyrin and Phthalocyanine Chemistry

paper · doi:10.1039/d4qi02972k

openalex publication_date 2024/12/17 · openalex created_date 2024/12/18 · openalex updated_date 2026/08/01

Abstract

A bis-Fe( iii )-μ-oxo-porphyrin dimer where the two porphyrin units are covalently bridged by a rigid ethene linker has been utilized to modulate spin coupling via an oxo-group upon stepwise oxidations.

Citations

• Density Functional Theory of Electronic Structure

Discussions

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