Magnetic dynamics and exchange coupling in dinuclear lanthanide complexes bridged by naphthoquinone and anthraquinone radicals

2025/01/01 by Dimitris I. Alexandropoulos, Kuduva R. Vignesh, Luı́s Cunha-Silva +1 · 1 voice
Materials Science · Chemistry · #Magnetism in coordination complexes #Lanthanide and Transition Metal Complexes #Molecular spectroscopy and chirality

paper · pdf · doi:10.1039/d5qi01477h

openalex publication_date 2025/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/25

Abstract

The first dinuclear Dy III complexes bridged by naphtho- and anthraquinone radicals are reported, showing strong Dy-radical ferromagnetic coupling and SMM behavior, and highlighting the key role of redox-active ligands in modulating magnetic dynamics.

Citations

• Dispersion and Absorption in Dielectrics I. Alternating Current Characteristics
• <i>Mercury</i>: visualization and analysis of crystal structures
• <i>ShelXle</i>: a Qt graphical user interface for<i>SHELXL</i>

Discussions

• 🧲 Magnetic dynamics and exchange coupling in dinuclear lanthanide complexes by Kim R. Dunbar et al. — Radical-bridged Dy³⁺ complexes show SMM behavior with ferromagnetic Dy–radical coupling. doi.org/ [bsky, 1 points, 0 comments]

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