Mechanisms of Cu/DMAP-cocatalyzed and DMAP-catalyzed C–N decarboxylative cross-coupling reactions

2025/01/01 by Ruisheng Zhao, Chaomin Hao, Dan Liu +2 · 1 voice
Chemistry · #Asymmetric Hydrogenation and Catalysis #Catalytic Alkyne Reactions #Catalytic C–H Functionalization Methods

paper · doi:10.1039/d4qo02352h

openalex publication_date 2025/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/05/21

Abstract

DMAP can assist the transfer of N 3 − from the initial azidoformate species to the formed acyl azide intermediates and facilitate the Cu/DMAP-cocatalyzed and DMAP-catalyzed C–N decarboxylative cross-coupling reactions.

Citations

• Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals
• Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density
• Density-functional thermochemistry. III. The role of exact exchange
• The calculation of small molecular interactions by the differences of separate total energies. Some procedures with reduced errors
• Decarboxylative Halogenation of Organic Compounds
• C–H Activation: Toward Sustainability and Applications

Discussions

• 🔊Organic Chemistry Frontiers Issue 08 is online now! 👉On the front cover is the #research from Zizhong Liu, Yongsheng Bao et al. 🔗Mechanisms of Cu/DMAP-cocatalyzed and DMAP-catalyzed C–N decarbo [bsky, 0 points, 0 comments]

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