Palladium/photoredox catalysis for a decarboxylative radical C(sp ³ )–C(sp ³ ) cross-coupling reaction of γ-methylidene-δ-valerolactones with alkyl carboxylic acids

2025/01/01 by Ran Song, Jiaxing Li, Lin Li +5 · 1 voice
Chemistry · #Radical Photochemical Reactions #Catalytic C–H Functionalization Methods #Sulfur-Based Synthesis Techniques

paper · pdf · doi:10.1039/d5qo01005e

openalex publication_date 2025/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/31

Abstract

A radical decarboxylative Csp 3 –Csp 3 cross-coupling of γ-methylidene-δ-valerolactones and non-preactivated alkyl carboxylic acids was developed by combining photocatalysis and palladium catalysis.

Citations

• Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
• Transition Metal-Catalyzed Organic Reactions under Visible Light: Recent Developments and Future Perspectives
• Decarboxylative Halogenation of Organic Compounds
• Visible Light-Induced Transition Metal Catalysis

Discussions

• 📖 Palladium/photoredox catalysis for decarboxylative radical C(sp³)–C(sp³) cross-coupling reaction of γ-methylidene-δ-valerolactones with alkyl carboxylic acids Wen Si , Jian Lv et al. 🔗 doi.org/ [bsky, 1 points, 0 comments]

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