2025/03/01 by И. Р. Рамазанов, I. R. Ramazanov, Rita N. Kadikova +5 · 1 citation
Chemical Engineering · Chemistry · #Carbon dioxide utilization in catalysis #Catalytic Cross-Coupling Reactions #Organometallic Complex Synthesis and Catalysis
paper · pdf · doi:10.59761/rcr5158
crossref issued 2025/03/01 · crossref published 2025/03/01 · crossref published-online 2025/03/01 · crossref published-print 2025/03/01 · openalex publication_date 2025/03/01 · crossref created 2025/03/14 · crossref deposited 2025/07/28 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28 · crossref indexed 2026/08/03
Over the last 10 years, conceptually new results have been obtained in the field of unsaturated organozinc reagents; these results need to be analyzed and integrated. This review systematically considers data on the catalytic carbozincation reactions of alkynes, which give alkenyl organozinc compounds, highly reactive intermediates for the synthesis of functionally substituted olefins. The reactions catalyzed by copper, iron, cobalt, nickel, and rhodium complexes are described. A separate part of the review addresses the catalytic reactions initiated by zirconium and titanium compounds. The reaction conditions are indicated; in some cases, putative reaction mechanisms are discussed.<br> The bibliography includes 135 references.