2025/06/01 by У. М. Джемилев, U. M. Dzhemilev, Vladimir A. D’yakonov +1
Chemistry · #Advanced Synthetic Organic Chemistry #Asymmetric Synthesis and Catalysis #Chemical synthesis and alkaloids
paper · doi:10.59761/rcr5172
crossref issued 2025/06/01 · crossref published 2025/06/01 · crossref published-online 2025/06/01 · crossref published-print 2025/06/01 · openalex publication_date 2025/06/01 · crossref created 2025/06/20 · crossref deposited 2025/07/28 · openalex created_date 2025/10/10 · crossref indexed 2026/08/03 · openalex updated_date 2026/08/04
The review integrates, for the first time, the results of studies carried out in the world over the last 15–20 years on the development and application of fundamental organometallic reactions catalyzed by transition metal complexes that give new carbon–carbon, metal–carbon, and heteroatom–carbon bonds and on the synthesis of small, medium, and large metallacarbocycles containing main group metals (Mg, Al, B). The review addresses data on the use of new organometallic reactions and metallacarbocycles for the preparation of practically important synthetic analogues of natural compounds, Z,Z-diene and Z,Z,Z-triene unsaturated carboxylic acids, acetogenins, lembehynes, regular isoprenoids, insect pheromones with a record high sterechemical purity, as well as toxins, heterocycles, and biaryls, the synthesis of which by other methods requires the use of expensive reagents or multistep procedures. <br> The bibliography includes 217 references.