2026/01/01 by Aleksandra Pacanowska, Gaja Wota, Małgorzata Jasiurkowska-Delaporte +11 · 1 voice
Chemistry · Engineering · Materials Science · #Magnetism in coordination complexes #Metal-Organic Frameworks: Synthesis and Applications #Organic Light-Emitting Diodes Research
paper · doi:10.1039/d5nr03887a
openalex publication_date 2026/01/01 · openalex created_date 2026/02/25 · openalex updated_date 2026/07/27
-styrene) (P2VP-PS). The embedded coordination compound is characterized by reversible metal-to-metal charge transfer, which can be triggered by changes in temperature, humidity, or pressure, and under ambient conditions, it can exist in three phases differing in color and magnetic susceptibility. However, its crystalline form is brittle and easily damaged by contact with liquid water. The composite mats combine the switchability of the coordination chain with the favorable mechanical properties of the organic polymer matrix. Most importantly, the use of the hydrophobic PCL polymer provides full protection from water damage. The morphology of the mats and the influence of the polymer matrix on the properties of the embedded compound have been studied by electron microscopy (SEM and TEM), X-ray absorption (XAS) and Raman spectroscopy, PXRD, dynamic vapor sorption (DVS), and magnetic measurements.