2013/07/01 by John D Stempien, John D. Stempien, David Carpenter +4
Engineering · Materials Science · #Advanced ceramic materials synthesis #Advanced materials and composites #Nuclear Materials and Properties
paper · doi:10.13182/nt12-86
crossref issued 2013/07/01 · crossref published 2013/07/01 · crossref published-print 2013/07/01 · openalex publication_date 2013/07/01 · crossref created 2014/05/08 · crossref published-online 2017/03/22 · crossref deposited 2017/09/19 · openalex created_date 2025/10/10 · crossref indexed 2026/07/31 · openalex updated_date 2026/08/01
Silicon carbide possesses a high melting point, low chemical activity, no appreciable creep at high temperatures, and a low neutron absorption cross section, making it an attractive material to investigate for use as fuel cladding in light water reactors. The cladding design investigated herein consists of three layers: an inner monolith of SiC, a central composite layer of SiC fibers infiltrated with SiC, and an outer SiC coating to protect against corrosion. The inner monolith provides strength and hermeticity for the tube, and the composite layer adds strength to the monolith while providing a pseudo-ductile failure mode in the hoop direction. The tube may be sealed by bonding SiC end caps to the SiC tube. A number of samples were irradiated in a test loop simulating pressurized water reactor coolant and neutronic conditions at the Massachusetts Institute of Technology research reactor. Postirradiation hoop stress testing via internal pressurization revealed 10% to 60% strength reduction due to physical properties mismatches between the three layers and corrosion. Weight loss measurements indicated that some irradiation-assisted corrosion occurred. Scanning electron microscope analysis allowed determination of the fracture mechanisms for specimens ruptured during hoop testing. The thermal diffusivities of the as-fabricated three-layer tube samples were measured to be roughly three times lower than those of the as-fabricated monolith layer. With irradiation, the thermal diffusivities decreased by factors of 14 and 8 for the monolith and three-layered samples, respectively. This change may be attributed to radiation damage and the formation of a silica layer on the sample surface. Anisotropic swelling of the bonded α-SiC blocks was sufficient to fail five of the six bond test specimens after a 1.5-month irradiation. Two of each of the calcium aluminate and Ti foil bonded samples failed. One of two TiC/SiC bond samples survived.