Breaking C–C (sp 3 –sp 3 ) σ bonds in 1,4-diazabicyclo[2.2.2]octane (DABCO) by oxidation with antimony pentachloride

2026/01/01 by Lilia M. Baldauf, David Geraldo Villarreal, Guodong Rao +6 · 1 voice
Chemistry · #Chemical Reactions and Mechanisms #Organic Chemistry Cycloaddition Reactions #Structural and Chemical Analysis of Organic and Inorganic Compounds

paper · doi:10.1039/d5qo01513h

openalex publication_date 2026/01/01 · openalex created_date 2026/04/14 · openalex updated_date 2026/07/02

Abstract

The C–C σ bond cleavage of 1,4-diazabicyclooctane[2.2.2] (DABCO) has been facilitated using antimony pentachloride, characterized by EPR and SC-XRD, and explained using in silico methods.

Citations

• Visible Light-Driven Radical-Mediated C–C Bond Cleavage/Functionalization in Organic Synthesis
• Transition-Metal-Catalyzed, Coordination-Assisted Functionalization of Nonactivated C(sp3)–H Bonds
• Synthesis through C(sp3)–C(sp2) Bond Scission in Alkenes and Ketones
• Quantum Chemistry on Graphical Processing Units. 2. Direct Self-Consistent-Field Implementation
• Quantum Chemistry on Graphical Processing Units. 1. Strategies for Two-Electron Integral Evaluation

Discussions

• 🔔Welcome to Issue 13! Please read the Outside Front Cover article: Breaking C–C (sp³–sp³) σ bonds in 1,4-diazabicyclo[2.2.2]octane (DABCO) by oxidation with antimony pentachloride by Alan L. Balch [bsky, 0 points, 1 comments]

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