Transition-metal-free approaches to poly(aminoboranes) and poly(phosphinoboranes): mechanisms, advances, and future directions

2025/11/06 by Matthew A. Wiebe, Anne Staubitz · 1 voice
Chemistry · #Asymmetric Hydrogenation and Catalysis #Catalytic Cross-Coupling Reactions #Organoboron and organosilicon chemistry

paper · pdf · doi:10.1039/d5qi01935d

openalex created_date 2025/11/06 · openalex publication_date 2025/11/06 · openalex updated_date 2026/07/22

Abstract

The transition-metal-free syntheses of poly(aminoboranes) and poly(phosphinoboranes) are reviewed. These strategies focus on the generation of reactive aminoboranes or phosphinoboranes in situ , which then undergo polymerization.

Citations

• Heterogeneous Single-Site Catalysts for Olefin Polymerization
• Molecular Double‐Bond Covalent Radii for Elements Li–E112

Discussions

• Review article by Matthew A. Wiebe and Anne Staubitz. #UniversityofKiel This review article discusses the new design principles and polymer synthetic concepts. #polyaminoboranes #polyphosphinoborane [bsky, 1 points, 0 comments]

Related

• Ambient and metal-free C(sp 2 )–C(sp 3 ) cross-coupling polymerization of dichalcones and activated methylenes to prepare clusteroluminescent polyarylacrylonitriles
• A new class of ligand derived from the reactions of bis(dialkylphosphino)amines and 9-diazofluorene: preparation, structure and reactivity
• Synthesis of high molecular weight copolymers of isobutylene and bio-renewable β-pinene via cationic polymerization
• Biobased chemical recycling: aminolysis of PET using renewable reagents and monomers to synthesize new semi-aromatic polyamides
• Poly(2-pyridyl)phosphines: Separation-Friendly Reagents for the Mitsunobu and Appel Reactions