2025/03/03 by Or Eivgi, Clara Vazquez‐Martel, Jaroslav Lukeš +1 · 1 voice
Engineering · #Additive Manufacturing and 3D Printing Technologies #Injection Molding Process and Properties #Manufacturing Process and Optimization
paper · pdf · doi:10.26434/chemrxiv-2025-3cql6
openalex publication_date 2025/03/03 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/22
The characterization of mechanical properties in soft 3D printed materials at the microscale remains a significant challenge due to the lack of standardized methodologies. To address this issue, a microscale nanoindentation protocol for elastomeric 3D printed microstructures is developed, optimized, and benchmarked. Herein, a conospherical indenter tip (r = 10.26 µm), a modified trapezoidal displacement profile with lift-off segments to capture adhesion interactions, and the nano-Johnson-Kendall-Roberts model for data analysis is employed. The protocol is optimized and verified using four newly developed PDMS-based inks for two-photon 3D laser printing. The results are compared to a state-of-the-art literature protocol that uses a Berkovich tip and the Oliver-Pharr model. It is shown that adhesion forces play a significant role in mechanical properties overestimation, showing differences of up to 80% between the different protocols. This study highlights the importance of carefully selecting characterization protocol to yield comparable results between studies. By providing a standardized protocol, it paves the way for straightforward and accurate characterization of mechanical properties in soft 3D printed materials at the microscale.