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Bromide and Other Halide Ion Removal From Drinking Waters Using Silver‐Amended Coagulation

2018/05/17 by Wenhui Gan, Arjun K. Venkatesan, Onur G. Apul +4
Engineering · Environmental Science · #Environmental remediation with nanomaterials #Mercury impact and mitigation studies #Water Treatment and Disinfection

paper · doi:10.1002/awwa.1049

crossref issued 2018/05/17 · crossref published 2018/05/17 · crossref published-online 2018/05/17 · openalex publication_date 2018/05/17 · crossref created 2018/05/17 · crossref published-print 2018/06/01 · crossref deposited 2023/09/17 · openalex created_date 2025/10/10 · crossref indexed 2026/07/29 · openalex updated_date 2026/08/01

Abstract

High bromide ion concentrations are of concern because of formation of brominated disinfection byproducts in drinking water, which may be more toxic than their chlorinated analogs. Jar tests dosed with alum and silver were performed on several water samples with chloride‐to‐bromide (Cl:Br) ratios ranging from 15 to 866 mg Cl/mg Br. In lower‐chloride waters (15 mg Cl/mg Br), silver‐amended coagulation (SAC) removed 20–90% of the initial bromide. In higher‐chloride water (525 mg Cl/mg Br), a silver dose of 15 mol Ag/mol Br achieved 40% bromide removal. Iodide and chloride removal also occurred during silver addition. SAC did not influence total organic carbon or turbidity removal, and residual silver was below the secondary maximum contaminant level but was successful in decreasing trihalomethane (THM) formation from 44 to 28 μg/L by shifting away from brominated THM species. SAC may only be applicable and cost‐effective in a narrow range of waters with lower Cl:Br ratios, and other technologies should be developed for waters with >300 mg Cl/mg Br.

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