2004/06/29 by R. Englman, A. Yahalom
Physics and Astronomy · #physics.chem-ph
published as chapter of the volume "The Role of Degenerate States in Chemistry" edited by M. Baer and G. Billing in Adv. Chem. Phys. Vol. 124 (John Wiley & Sons 2002) · 79 pages, 6 figures
arxiv created 2004/06/29 · arxiv updated 2009/12/01
A review is given of phase properties in molecular wave functions, composed of a number of (and, at least, two) electronic states that become degenerate at some nearby values of the nuclear configuration. Apart from discussing phases and interference in classical (non-quantal) systems, including light-waves, the review looks at the constructability of complex wave functions from observable quantities ("the phase problem"), at the controversy regarding quantum mechanical phase-operators, at the modes of observability of phase and at the role of phases in some non-demolition measurements. Advances in experimental and (especially) theoretical aspects of Aharonov-Bohm and topological (Berry) phases are described, including those involving two-electron and relativistic systems. Several works in the phase control and revivals of molecular wave-packets are cited as developments and applications of complex-function theory. Further topics that this review touches on are: coherent states, semiclassical approximations and the Maslov index. The interrelation between time and the complex state is noted in the contexts of time delays in scattering, of time-reversal invariance and of the existence of a molecular time-arrow.