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Modeling and Applications of Electrochemical Impedance Spectroscopy (EIS) for Lithium-ion Batteries

2020/02/26 by Woosung Choi, Heon‐Cheol Shin, Ji Man Kim +2 · 5 citations
Engineering · #Advanced Battery Materials and Technologies #Advanced Battery Technologies Research #Advancements in Battery Materials

paper · pdf · doi:10.33961/jecst.2019.00528

openalex publication_date 2020/02/26 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/31

Abstract

As research on secondary batteries becomes important, interest in analytical methods to examine the condition of secondary batteries is also increasing. Among these methods, the electrochemical impedance spectroscopy (EIS) method is one of the most attractive diagnostic techniques due to its convenience, quickness, accuracy, and low cost. However, since the obtained spectra are complicated signals representing several impedance elements, it is necessary to understand the whole electrochemical environment for a meaningful analysis. Based on the understanding of the whole system, the circuit elements constituting the cell can be obtained through construction of a physically sound circuit model. Therefore, this mini-review will explain how to construct a physically sound circuit model according to the characteristics of the battery cell system and then introduce the relationship between the obtained resistances of the bulk (R b ), charge transfer reaction (R ct ), interface layer (R SEI ), diffusion process (W) and battery characteristics, such as the state of charge (SOC), temperature, and state of health (SOH).

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