2025/02/10 by Calles, Simon, Heitjans, Paul, Börger, Alexander
#500 | Naturwissenschaften #600 | Technik #Impedance spectroscopy #PHEV2 format #automotive applications #lithium-ion batteries
paper · doi:10.15488/18503
Prismatic PHEV2 form-factor lithium-ion cells with a nominal capacity of 25 Ah (as used for automotive applications) have been studied with electrochemical impedance spectroscopy (EIS). The data was evaluated using electrical equivalent circuits. Mathematical modeling, system identification, and the determination of model parameters of the lithium-ion cell were also carried out. While a study of the influence of temperature and state-of-charge (SOC) performed using pristine lithium-ion cells showed a nonlinear relationship between temperature and the fits for different RC elements. Finally, the interdependency of parameters determined by EIS has been demonstrated for cells in different aging regimes (cyclic vs. non-cyclic aging) relevant for automotive requirements use cases.