Atropisomers beyond the C–C axial chirality: Advances in catalytic asymmetric synthesis

2022/05/06 by Guang‐Jian Mei, Guang-Jian Mei, Wai Lean Koay +3 · 11 citations
Chemistry · #Axial and Atropisomeric Chirality Synthesis #Molecular spectroscopy and chirality #Synthesis and Properties of Aromatic Compounds

paper · doi:10.1016/j.chempr.2022.04.011

openalex publication_date 2022/05/06 · crossref created 2022/05/06 · crossref issued 2022/07/01 · crossref published 2022/07/01 · crossref published-print 2022/07/01 · openalex created_date 2025/10/10 · crossref deposited 2025/11/07 · crossref indexed 2026/07/29 · openalex updated_date 2026/07/30

Citations

• Atroposelective transformation of axially chiral (hetero)biaryls. From desymmetrization to modern resolution strategies
• Recent Advances in Catalytic Asymmetric Construction of Atropisomers
• Synthesis of Atropisomers by Transition-Metal-Catalyzed Asymmetric C–H Functionalization Reactions

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• Design and construction of difunctionalized C−N atropisomers via lipase-catalyzed desymmetrization and kinetic resolution of N-naphthol-carbazoles
• Isothiourea catalysed enantioselective generation of point and axially chiral iminothia- and iminoselenazinanones
• The Atroposelective Iodination of 2-Amino-6-arylpyridines Catalyzed by Chiral Disulfonimides Actually Proceeds via Brønsted Base Catalysis: A Combined Experimental, Computational, and Machine-Learning Study
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