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Equilibrium Free Energies from Nonequilibrium Processes

1998/02/13 by C. Jarzynski
Physics and Astronomy · #cond-mat.stat-mech #physics.chem-ph

paper · pdf

published as Acta Physica Polonica B 29, 1609 (1998) · Conference talk in Zakopane, Poland; 11 pages + 3 figures

arxiv created 1998/02/13 · arxiv updated 2009/11/30

Abstract

A recent result, relating the (irreversible) work performed on a system during a non-quasistatic process, to the Helmholtz free energy difference between two equilibrium states of the system, is discussed. A proof of this result is given for the special case when the evolution of the system in question is modelled by a Langevin equation in configuration space.

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