The stereochemistry of substitution at S( <scp>vi</scp> )

2025/01/01 by Oliver L. Symes, James A. Bull · 2 voices · 1 citation
Chemistry · #Chemical Thermodynamics and Molecular Structure #Chemistry and Stereochemistry Studies #History and advancements in chemistry

paper · pdf · doi:10.1039/d5qo01043h

openalex publication_date 2025/01/01 · openalex created_date 2025/08/21 · openalex updated_date 2026/06/26

Abstract

This review examines the mechanism and stereochemical outcome of substitution reactions at chiral S( vi ) electrophiles.

Citations

• Sulfoximines as Rising Stars in Modern Drug Discovery? Current Status and Perspective on an Emerging Functional Group in Medicinal Chemistry
• An Update on the Nitrogen Heterocycle Compositions and Properties of U.S. FDA-Approved Pharmaceuticals (2013–2023)

Cited by

• Regioselective synthesis of aza-saccharins <i>via</i> anionic [1,4] Fries-type rearrangement of aryl sulfonimidoyl fluorides

Discussions

• As asymmetric sulfur(VI) derivatives become more prevalent in the chemical sciences, especially in aza-derivatives, sulfoximines, sulfonimidamides, we have reviewed "The stereochemistry of substitutio [bsky, 6 points, 0 comments]
• 📘 The stereochemistry of substitution at S(VI) ✨ by James A. Bull 𝘦𝘵 𝘢𝘭. Insights into stereochemical outcomes in SuFEx & S(VI) substitution ⚗️🔄 #SulfurChemistry #Stereochemistry #ClickChem 🔗 [bsky, 2 points, 0 comments]

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