β‐Cyclodextrin‐Modified Diphosphanes as Ligands for Supramolecular Rhodium Catalysts

1997/05/02 by Manfred T. Reetz, Siegfried R. Waldvogel · 1 citation
Chemistry · #Asymmetric Hydrogenation and Catalysis #Cyclopropane Reaction Mechanisms #Organometallic Complex Synthesis and Catalysis

paper · doi:10.1002/anie.199708651

openalex publication_date 1997/05/02 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

Hydrogenation and hydroformylation occur highly selectively with rhodium complexes of β-cyclodextrin-modified phosphanes (such as 1) as catalysts. These are of interest particularly for industrial applications, in which transition-metal catalysis and phase-transfer catalysis are combined in one and the same catalyst.

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• Green Organometallic Chemistry

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